长白山天池火山千年大喷发岩浆含水量研究——熔融包裹体含水量的红外光谱测试   总被引：1，自引：0，他引：1  

李霓  Nicole  METRICH  樊祺诚 《岩石学报》2006,22(6):1465-1472

长白山天池火山在公元一千年左右曾发生过大规模喷发，其产物为大面积分布的灰白色碱流质浮岩和碎屑流，在其斑晶矿物橄榄石、钙铁辉石和碱性长石中均可见到熔融包裹体。在最主要的斑晶矿物——碱性长石中含有数量众多且个体也较大的熔融包裹体，多数含有一个以上的气泡，其中部分含有子晶，根据形貌特征的不同可分为截然不同的两组包裹体。这些熔融包裹体带有大量喷发前地下岩浆的信息，成为研究地下深部的岩浆在复杂的溢流-爆炸喷发中所发生变化的最好媒介。也是本文的研究对象，通过其中挥发份尤其是水的含量，可以推知天池火山发生大喷发的原因。经Nicolet Magna-IR 550红外光谱仪测定，这些熔融包裹体的含水量较高，达1．6％-3．6％，为当时天池火山发生了巨大规模爆炸喷发的原因提供了强有力的证据。但目前红外光谱仪的应用范围还比较有限，有待今后拓宽其应用领域。  相似文献   

Arsenic fixation on iron-hydroxide-rich and plant litter-containing sediments in natural environments   总被引：2，自引：0，他引：2  

Andreas Fritzsche  Holger Dienemann  Ernst Gert Dudel 《Environmental Geology》2006,51(1):133-142

Iron-hydroxide-rich and plant litter-containing sediments from natural sites contaminated with uranium mine tailing leachates were examined for their ability to adsorb arsenic. The samples with high contents of iron hydroxides (Fe_total concentration, >300 g kg⁻¹) exhibited remarkable fixation of arsenic (up to 40 g As kg⁻¹). This value corresponded approximately to the supersaturation point for natural iron hydroxides under the present conditions, and it was significantly lower than the value found for synthetic iron hydroxides. There was a strong correlation (R=0.8999) between the concentration of iron and that of arsenic at low arsenic contents, indicating adsorption on strong binding sites. Although all the samples had noticeable contents of organic carbon (plant litter), calcium, and manganese, no obvious effect of these elements on arsenic fixation could be detected. The amount of iron hydroxides was found the only fixation-controlling parameter immediately below a leaching water source.  相似文献   

Calcium and magnesium‐limited dolomite precipitation at Deep Springs Lake,California     

PATRICK MEISTER  CAROLINA REYES  WILL BEAUMONT  MIGUEL RINCON  LISA COLLINS  WILLIAM BERELSON  LOWELL STOTT  FRANK CORSETTI  KENNETH H. NEALSON 《Sedimentology》2011,58(7):1810-1830

Dolomite [Ca,Mg(CO₃)₂] precipitation from supersaturated ionic solutions at Earth surface temperatures is considered kinetically inhibited because of the difficulties experienced in experimentally reproducing such a process. Nevertheless, recent dolomite is observed to form in hypersaline and alkaline environments. Such recent dolomite precipitation is commonly attributed to microbial mediation because dolomite has been demonstrated to form in vitro in microbial cultures. The mechanism of microbially mediated dolomite precipitation is, however, poorly understood and it remains unclear what role microbial mediation plays in natural environments. In the study presented here, simple geochemical methods were used to assess the limitations and controls of dolomite formation in Deep Springs Lake, a highly alkaline playa lake in eastern California showing ongoing dolomite authigenesis. The sediments of Deep Springs Lake consist of unlithified, clay‐fraction dolomite ooze. Based on δ¹⁸O equilibria and textural observations, dolomite precipitates from oxygenated and agitated surface brine. The Na‐SO₄‐dominated brine contains up to 500 mm dissolved inorganic carbon whereas Mg²⁺ and Ca²⁺ concentrations are ca 1 and 0·3 mm , respectively. Precipitation in the subsurface probably is not significant because of the lack of Ca²⁺ (below 0·01 mm ). Under such highly alkaline conditions, the effect of microbial metabolism on supersaturation by pH and alkalinity increase is negligible. A putative microbial effect could, however, support dolomite nucleation or support crystal growth by overcoming a kinetic barrier. An essential limitation on crystal growth rates imposed by the low Ca²⁺ and Mg²⁺ concentrations could favour the thermodynamically more stable carbonate phase (which is dolomite) to precipitate. This mode of unlithified dolomite ooze formation showing δ¹³C values near to equilibrium with atmospheric CO₂ (ca 3‰) contrasts the formation of isotopically light (organically derived), hard‐lithified dolomite layers in the subsurface of some less alkaline environments. Inferred physicochemical controls on dolomite formation under highly alkaline conditions observed in Deep Springs Lake may shed light on conditions that favoured extensive dolomite formation in alkaline Precambrian oceans, as opposed to modern oceans where dolomites only form diagenetically in organic C‐rich sediments.  相似文献   

Post-collisional transition from calc-alkaline to alkaline volcanism during the Neogene in Oranie (Algeria): magmatic expression of a slab breakoff   总被引：2，自引：0，他引：2  

Christian Coulon  M'hamed Megartsi  Serge Fourcade  Ren C. Maury  Herv Bellon  Amina Louni-Hacini  Joseph Cotten  Alain Coutelle  Daniel Hermitte 《Lithos》2002,62(3-4):87-110

During the Neogene, a magmatic change from calc-alkaline to alkaline types occurred in all the regions surrounding the western Mediterranean. This change has been studied in Oranie (western Algeria). In this area, potassic to shoshonitic calc-alkaline andesites (with La/Nb ratios in the range 4–6) were mainly erupted between 12 and 9 Ma. They were followed (between 10 and 7 Ma) by basalts displaying geochemical features which are transitional between calc-alkaline and alkaline lavas (La/Nb=1–1.7). After a ca. 3-Ma quiescence period, volcanic activity resumed, with the eruption of OIB-type alkaline basalts (La/Nb=0.5–0.6), from 4 to 0.8 Ma. A combined geochemical approach, using incompatible elements and Sr, Nd and O isotopes, allows us to conclude that the transitional basalts derived from the melting of a heterogeneous mantle source, at the boundary between lithosphere and asthenosphere. We propose that melting of a previously subduction-modified lithospheric mantle occurred between 12 and 10 Ma, in response to the upwelling of hot asthenosphere flowing up into an opening gap above a detached sinking slab. As a result, calc-alkaline magmas were formed. From 10 to 7 Ma, the transitional basalts were generated through melting of the boundary mantle zone between the lithosphere and the upwelling asthenosphere. During that stage, the contribution of the lithospheric source was still predominant. Then, as sinking of the oceanic slab progressed, the increasing uprise of the asthenosphere led to the formation and emplacement (from 4 to 0.8 Ma) of typical within-plate alkaline basalts derived from a plume-modified asthenospheric mantle.  相似文献   

安棚碱矿地层自然漂移规律研究及在钻井设计中的应用          下载免费PDF全文

陈博安唐大鹏  郭中峰吴天乾 《探矿工程》2001,(6):49-51

依据测井资料对安棚碱矿地层自然漂移规律统计分析，进行井身剖面设计，并运用回归理论确定水平位移与垂直井深相关方程，提出了井口坐标设计方案。经实际应用，缩短了钻井周期，提高了钻机月速及机械钻速。  相似文献   

大同第四纪火山群的活动特点     

Zhang Shimin Dou Suqin 《地壳构造与地壳应力文集》1997,(1)

一、引言大同第四纪火山群位于山西省大同县和阳高县境内(图1),包括近5年来在大峪口,秋林地区首次发现的6个小火山。该火山群大、小火山共计31个。大同火山群南以六棱山北麓断裂为界,分布于大同盆地东部的第四纪沉积区范围。火山群南侧的六棱山和北部的小北山是由前寒武花岗片麻岩组成的山地。  相似文献   

The alkaline–peralkaline granitic post-collisional Tin Zebane dyke swarm (Pan-African Tuareg shield, Algeria): prevalent mantle signature and late agpaitic differentiation     

Zakia Hadj-Kaddour  Jean-Paul Li  geois  Daniel Demaiffe  Renaud Caby 《Lithos》1998,45(1-4):223-243

The Tin Zebane dyke swarm was emplaced at the end of the Pan-African orogeny along a mega-shear zone separating two contrasting terranes of the Tuareg shield. It is located along the western boundary of the Archaean In Ouzzal rigid terrane, but inside the adjacent Tassendjanet terrane, strongly remobilized at the end of the Precambrian. The Tin Zebane swarm was emplaced during post-collisional sinistral movements along the shear zone at 592.2±5.8 Ma (19WR Rb–Sr isochron). It is a dyke-on-dyke system consisting of dykes and stocks of gabbros and dykes of metaluminous and peralkaline granites. All rock types have Sr and Nd isotopic initial ratios (Sr_i=0.7028 and _Nd=+6.2) typical of a depleted mantle source, similar to the prevalent mantle (PREMA) at that period. No crustal contamination occurred in the genesis of the Tin Zebane swarm. Even the samples showing evidence of fluid interaction (essentially alkali mobility) have the same isotopic signature. The peralkaline granites have peculiar geochemical characteristics that mimic subduction-related granites: this geochemical signature is interpreted in terms of extensive differentiation effects due to late cumulates comprising aegirine, zircon, titanite, allanite and possibly fergusonite, separated from the liquid in the swarm itself due to magmatic flow turbulence. The Tin Zebane dyke swarm is thus of paramount importance for constraining the differentiation of mantle products to generate highly evolved alkaline granites without continental crust participation, in a post-collisional setting.  相似文献   

冀北雾灵山碱性花岗质杂岩的岩石学,成因类型及构造意义   总被引：7，自引：5，他引：7  

许保良  阎国翰 《岩石学报》1996,12(1):145-155

河北雾灵山碱性花岗质杂岩主要由似斑状碱长正长岩、碱长正长斑岩、碱性石英正长岩和碱性石英正长班岩组成，是华北地区燕山晚期岩浆活动的代表。本文系统报道了它的地质学、岩相学、岩石化学和地球化学的特征，讨论了它的成因类型归属和所代表的大地构造环境问题。这些资料表明；该杂岩体形成于白垩纪早期，是一个剥蚀程度较小、定位于浅成环境的硅饱和碱性－过碱性岩杂岩体，属裂谷－类裂谷Ａ型花岗岩类，它的出现表明华北地区早白垩纪时期曾处于板内裂谷－类裂谷的引张环境。  相似文献   

Geology and K-Ar dating of the Tuxtla Volcanic Field,Veracruz, Mexico     

Stephen A Nelson  Erika Gonzalez-Caver 《Bulletin of Volcanology》1992,55(1-2):85-96

The Tuxtla Volcanic Field (TVF) is located on the coast of the Gulf of Mexico in the southern part of the state of Veracruz, Mexico. Volcanism began about 7 my ago, in the Late Miocene, and continued to recent times with historical eruptions in ad 1664 and 1793. The oldest rocks occur as highly eroded remnants of lava flows in the area surrounding the historically active cone of San Martín Tuxtla. Between about 3 and 1 my ago, four large composite volcanoes were built in the eastern part of the area. Rocks from these structures are hydrothermally altered and covered with lateritic soils, and their northern slopes show extensive erosional dissection that has widened preexisting craters to form erosional calderas. The eastern volcanoes are composed of alkali basalts, hawaiites, mugearites, and benmoreites, with less common calc-alkaline basaltic andesites and andesites. In the western part of the area, San Martín Tuxtla Volcano and its over 250 satellite cinder cones and maars produced about 120 km³ of lava over the last 0.8 my. A ridge of flank cinder cones blocked drainage to the north to form Laguna Catemaco. Lavas erupted from San Martín and its flank vents are restricted to compositions between basanite and alkali basalt. The alignment of major volcanoes and flank vents along a N55°W trend suggests an extensional stress field in the crust with a minimum compressional stress orientation of N35° E. In total, about 800 km³ of lava has been erupted in the TVF in the last 7 my. This gives a magma output rate of about 0.1 km³/1000 year, a value smaller than most composite cones, but similar to cinder cone fields that occur in central Mexico. Individual eruptions over the last 5000 years had volumes on the order of 0.1km³, with average recurrence intervals of 600 years. The alkaline compositions of the TVF lavas contrast markedly with the calc-alkaline compositions erupted in the subduction-related Mexican Volcanic Belt to the west, leading previous workers to suggest that the TVF is not related to subduction. Trace-element signatures of TVF lavas indicate, however, that they are probably related to subduction. We suggest that the alkaline character of the TVF lavas is the result of low degrees of melting of a mantle source coupled with a stress regime that allows these small-volume melts to reach the surface in the TVF.  相似文献   

华北克拉通南缘张士英岩体大陆动力学背景:来自地球化学、锆石U-Pb年龄和Hf同位素的证据     

段友强  张正伟  杨晓勇 《岩石学报》2015,31(7):1995-2008

张士英岩体位于华北克拉通南缘,岩体主要由石英正长岩组成。石英正长岩的LA-ICP-MS锆石U-Pb年龄为122.8±1.5Ma。其Si O2含量为66.04%~67.80%,Na2O+K2O=9.03%~10.97%,K2O=4.40%~6.37%,K2O/Na2O1属于钾质长英质岩石。A/CNK=1.26~1.58,A/NK=1.63~1.79属于过铝质岩石系列。石英正长岩的Mg#变化范围在12.9~39.4。富集LREE亏损HREE,轻重稀土分异明显,(La/Yb)N=15.48~21.12,Eu呈弱的负异常(δEu=0.54~0.99)。富集Rb、K、Th、U等大离子亲石元素,亏损Nb、Ta、P、Ti等高场强元素。张士英石英正长岩岩浆锆石εHf(t)集中在-17.6~-13.9,Hf两阶段模式年龄tDM2集中在1.7~1.9Ga。石英正长岩的岩浆Zr饱和温度高(936~998℃)。地球化学及同位素显示张士英石英正长岩源区主要为古老的壳源物质,并有少量年轻组分加入,这种年轻组分是幔源物质。岩体形成于拉张性构造环境下,拉张性的环境导致了幔源物质的上涌,底侵下地壳使其发生部分熔融。形成时代正好位于华北克拉通破坏峰期,张士英石英正长岩正是这一地质事件的响应。  相似文献